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The IK-CAPE Thermodynamics-Module allows the calculation of thermodynamic properties. There is a handbook of equations that can be implemented in pathsim. It makes sense to implement these models to have a robust first set of blocks for the chemical engineering toolbox.
Webpage:
https://dechema.de/en/Analysis+_+Consulting/Engineering+Software/IK_CAPE+THERMO-p-40.html
Handbook:
https://dechema.de/dechema_media/Downloads/Informationssysteme/IK_CAPE_Equations-p-888.pdf
Model description format:
https://dechema.de/en/Analysis+_+Consulting/Engineering+Software/IK_CAPE+PPDX.html