diff --git a/fe/fe-core/src/main/java/org/apache/doris/alter/MaterializedViewHandler.java b/fe/fe-core/src/main/java/org/apache/doris/alter/MaterializedViewHandler.java
index 77fb98b3d70ec7..a197660f284c28 100644
--- a/fe/fe-core/src/main/java/org/apache/doris/alter/MaterializedViewHandler.java
+++ b/fe/fe-core/src/main/java/org/apache/doris/alter/MaterializedViewHandler.java
@@ -40,6 +40,7 @@
 import org.apache.doris.catalog.Tablet;
 import org.apache.doris.catalog.TabletInvertedIndex;
 import org.apache.doris.catalog.TabletMeta;
+import org.apache.doris.catalog.Type;
 import org.apache.doris.common.AnalysisException;
 import org.apache.doris.common.Config;
 import org.apache.doris.common.DdlException;
@@ -904,6 +905,12 @@ public List<Column> checkAndPrepareMaterializedView(AddRollupOp addRollupOp, Ola
                         throw new DdlException("Invalid column order. key should before all values: " + rollupColName);
                     }
 
+                    // BE sorts rollup rows by the duplicate keys, which these types cannot be compared on.
+                    if (isKey && baseColumn.getType().isOnlyMetricType()) {
+                        throw new DdlException("Column[" + rollupColName + "] can not be used as a duplicate key "
+                                + "of rollup. " + Type.OnlyMetricTypeErrorMsg);
+                    }
+
                     Column oneColumn = new Column(baseColumn);
                     if (isKey) {
                         hasKey = true;
diff --git a/regression-test/data/rollup_p0/test_rollup_dup_key_type.out b/regression-test/data/rollup_p0/test_rollup_dup_key_type.out
new file mode 100644
index 00000000000000..8d6a54da2b1b2f
--- /dev/null
+++ b/regression-test/data/rollup_p0/test_rollup_dup_key_type.out
@@ -0,0 +1,5 @@
+-- This file is automatically generated. You should know what you did if you want to edit this
+-- !rollup_s --
+x	1	10
+y	2	20
+
diff --git a/regression-test/suites/rollup_p0/test_rollup_dup_key_type.groovy b/regression-test/suites/rollup_p0/test_rollup_dup_key_type.groovy
new file mode 100644
index 00000000000000..e21cf756cfc6ef
--- /dev/null
+++ b/regression-test/suites/rollup_p0/test_rollup_dup_key_type.groovy
@@ -0,0 +1,70 @@
+// Licensed to the Apache Software Foundation (ASF) under one
+// or more contributor license agreements.  See the NOTICE file
+// distributed with this work for additional information
+// regarding copyright ownership.  The ASF licenses this file
+// to you under the Apache License, Version 2.0 (the
+// "License"); you may not use this file except in compliance
+// with the License.  You may obtain a copy of the License at
+//
+//   http://www.apache.org/licenses/LICENSE-2.0
+//
+// Unless required by applicable law or agreed to in writing,
+// software distributed under the License is distributed on an
+// "AS IS" BASIS, WITHOUT WARRANTIES OR CONDITIONS OF ANY
+// KIND, either express or implied.  See the License for the
+// specific language governing permissions and limitations
+// under the License.
+
+// Explicit rollup duplicate keys must be sortable: FE rejects them up front instead of
+// letting the asynchronous rollup job fail in BE.
+suite("test_rollup_dup_key_type") {
+    sql "DROP TABLE IF EXISTS test_rollup_dup_key_type"
+    sql """
+        CREATE TABLE test_rollup_dup_key_type (
+            id INT,
+            v VARIANT,
+            a ARRAY<INT>,
+            m MAP<INT, INT>,
+            st STRUCT<x:INT>,
+            j JSON,
+            s STRING
+        ) DUPLICATE KEY(id) DISTRIBUTED BY HASH(id) BUCKETS 1
+        PROPERTIES ("replication_num" = "1")
+    """
+    sql """INSERT INTO test_rollup_dup_key_type SELECT 1, parse_to_variant('{"a": 10}'), [1], map(1, 1),
+            named_struct('x', 1), '{"a": 1}', 'x'"""
+    sql """INSERT INTO test_rollup_dup_key_type SELECT 2, parse_to_variant('{"a": 20}'), [2], map(2, 2),
+            named_struct('x', 2), '{"a": 2}', 'y'"""
+
+    for (String col : ["v", "a", "m", "st", "j"]) {
+        test {
+            sql "ALTER TABLE test_rollup_dup_key_type ADD ROLLUP r_${col} (${col}, id) DUPLICATE KEY(${col})"
+            exception "Column[${col}] can not be used as a duplicate key of rollup"
+        }
+    }
+
+    // A value column of the same types is still allowed after a sortable key.
+    sql "ALTER TABLE test_rollup_dup_key_type ADD ROLLUP r_s (s, id, v) DUPLICATE KEY(s)"
+    def state = ""
+    for (int i = 0; i < 120; i++) {
+        state = sql("SHOW ALTER TABLE ROLLUP WHERE TableName = 'test_rollup_dup_key_type' "
+                + "ORDER BY CreateTime DESC LIMIT 1")[0][8]
+        if (state == "FINISHED" || state == "CANCELLED") {
+            break
+        }
+        sleep(1000)
+    }
+    assertEquals("FINISHED", state)
+    order_qt_rollup_s "SELECT s, id, CAST(v['a'] AS INT) FROM test_rollup_dup_key_type"
+
+    sql "DROP TABLE IF EXISTS test_rollup_dup_key_type_create"
+    test {
+        sql """
+            CREATE TABLE test_rollup_dup_key_type_create (id INT, v VARIANT)
+            DUPLICATE KEY(id) DISTRIBUTED BY HASH(id) BUCKETS 1
+            ROLLUP (r_v (v, id) DUPLICATE KEY(v))
+            PROPERTIES ("replication_num" = "1")
+        """
+        exception "Column[v] can not be used as a duplicate key of rollup"
+    }
+}